Kinetics of Oxidation of Heterocyclic Compounds by Quinolinium Dichromate

Quinolinium dichromate in sulfuric acid oxidized heterocyclic aldehydes (to the corresponding acids) and heterocyclic carboxylic acids (to the corresponding hydroxy-substituted acids) in acetic acid-water medium (vol. ratio, v(water)/v(acetic acid) = 50:50). The kinetic results supported a mechanist...

Full description

Saved in:
Bibliographic Details
Published inCroatica chemica acta Vol. 83; no. 3; p. 291
Main Authors Saunte, Hauzachin, Chaubey, Girija S, Mahanti, Mahendra K
Format Journal Article
LanguageEnglish
Published Zagreb Croatica Chemica Acta, Croatian Chemical Society 01.10.2010
Subjects
Chemical compounds
Kinetics
Oxidation
Online AccessGet full text

Cover

More Information
Summary:Quinolinium dichromate in sulfuric acid oxidized heterocyclic aldehydes (to the corresponding acids) and heterocyclic carboxylic acids (to the corresponding hydroxy-substituted acids) in acetic acid-water medium (vol. ratio, v(water)/v(acetic acid) = 50:50). The kinetic results supported a mechanistic pathway proceeding via a rate-determining decomposition of the chromate ester. [PUBLICATION ABSTRACT]
ISSN:0011-1643
1334-417X