NOVEL ROUTES TO BRANCHED-CHAIN AND AMINO-SUGARS FROM LEVOGLUCOSENONE, A CHIRAL SYNTHON AVAILABLE FROM CELLULOSE - STRUCTURAL DETERMINATION AT QUATERNARY CARBON-ATOM BY X-RAY-DIFFRACTION

Structural modifications of levoglucosenone, a chiral bicyclic enone available from cellulose, afford a novel access to branched-chain and amino-sugars: methyl, hydroxymethyl and aminomethyl derivatives at position 2. Assignment of the absolute configuration at the quaternary carbon atom has been de...

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Bibliographic Details
Published inHeterocycles Vol. 24; no. 4; pp. 931 - 934
Main Authors GELASMIALHE, Y, GELAS, J, AVENEL, D, BRAHMI, R, GILLIERPANDRAUD, H
Format Journal Article
LanguageEnglish
Published Tokyo Japan Inst Heterocyclic Chemistry 01.04.1986
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
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Summary:Structural modifications of levoglucosenone, a chiral bicyclic enone available from cellulose, afford a novel access to branched-chain and amino-sugars: methyl, hydroxymethyl and aminomethyl derivatives at position 2. Assignment of the absolute configuration at the quaternary carbon atom has been deduced from X-ray crystallographic data.
ISSN:0385-5414
1881-0942
DOI:10.3987/r-1986-04-0931