Hexaphenylbenzene-based polymers of intrinsic microporosity

Microporous polymers derived from the 1,2- and 1,4-regioisomers of di(3',4'-dihydroxyphenyl)tetraphenylbenzene have very different properties with the former being composed predominantly of cyclic oligomers whereas the latter is of high molar mass suitable for the formation of robust solve...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 47; no. 24; pp. 6822 - 6824
Main Authors Short, Rhys, Carta, Mariolino, Bezzu, C. Grazia, Fritsch, Detlev, Kariuki, Benson M., McKeown, Neil B.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 28.06.2011
Subjects
Chemistry
Chemistry, Multidisciplinary
Cyclic oligomers
Microporosity
Permeability
Physical Sciences
Polymers
Science & Technology
CRYSTALS
NETWORKS
ADSORPTION
DERIVATIVES
MOLECULES
CATIONS
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Summary:Microporous polymers derived from the 1,2- and 1,4-regioisomers of di(3',4'-dihydroxyphenyl)tetraphenylbenzene have very different properties with the former being composed predominantly of cyclic oligomers whereas the latter is of high molar mass suitable for the formation of robust solvent-cast films of high gas permeability.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc11717c