A new iodate-phosphate Pb2(IO3)(PO4) achieving great improvement in birefringence activated by (IO3)− groups

The first divalent-metal iodate-phosphate, Pb2(IO3)(PO4), has been prepared via the strategy of introducing (IO3)− into phosphate. The structure features a unique 3D network where [Pb(IO3)]∞+ and [Pb(PO4)]∞− layers are alternatively interconnected. The birefringence of Pb2(IO3)(PO4) is greatly incre...

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Published inChemical communications (Cambridge, England) Vol. 56; no. 4; pp. 635 - 638
Main Authors Zhang, Xiao-Han, Yang, Bing-Ping, Chen, Jin, Hu, Chun-Li, Fang, Zhi, Wang, Zujian, Mao, Jiang-Gao
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2020
Subjects
Birefringence
chemical reactions
Crystallography
divalent metals
iodates
lead
phosphates
Physical properties
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Summary:The first divalent-metal iodate-phosphate, Pb2(IO3)(PO4), has been prepared via the strategy of introducing (IO3)− into phosphate. The structure features a unique 3D network where [Pb(IO3)]∞+ and [Pb(PO4)]∞− layers are alternatively interconnected. The birefringence of Pb2(IO3)(PO4) is greatly increased to 0.060 at 1064 nm.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c9cc08739g