Strain Engineering to Boost Piezocatalytic Activity of BaTiO3

• Published in: ChemCatChem Vol. 15; no. 5
• Main Authors: Ai, Jun‐Di, Jin, Cheng‐Chao, Liu, Dai‐Ming, Zhang, Jin‐Tao, Zhang, Ling‐Xia
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 08.03.2023
• Subjects: Ball milling; Barium titanates; BaTiO3; Hydrogen evolution; Lattice strain; mechanism; piezocatalysis; Piezoelectricity; strain engineering
• ISSN: 1867-3880; 1867-3899
• DOI: 10.1002/cctc.202201316

Piezoelectric materials are sensitive to lattice strain, which is always related with their macroscopic properties. Therefore, it is of scientific significance to improve piezocatalytic performance by strain engineering and clarify the underlying mechanism. Herein, BaTiO3 (BTO) powder is fabricated by a solid‐state reaction and ball‐milling is employed to induce lattice strain in BTO. By prolonging ball‐milling time, the lattice strain increases, leading to an enhancement of tetragonality and piezocatalytic performance of BTO. The strain‐engineered BTO exhibited an excellent piezocatalytic activity, with a degradation rate constant k of ∼0.03 min−1 and a H2 evolution rate of 0.899 mmol g−1 h−1, which are 3 and 3.52 times those of the strain‐free one, respectively. The enhanced piezocatalytic performance can be ascribed to the improved piezoelectricity, piezoelectric polarization and adsorption activities for O2, OH and H of the strain‐engineered BTO. This work not only provides a simple and general method to improve piezocatalytic performance by strain engineering, but also unveils the enhancement mechanism. Lattice strain enhanced piezocatalytic performance: Ball‐milling, a simple and industrialized method, is employed to induce lattice strain in BaTiO3 (BTO) nanocrystals. The tetragonality, piezoelectricity, and surface adsorption ability of BTO are significantly increased by the ball‐milling induced strain. Consequently, the strain‐engineered BTO exhibits an improved piezocatalytic performance with a degradation rate constant k of ∼0.03 min−1 and a H2 evolution rate of 0.899 mmol g−1 h−1.