Acid Modification Method for Preparation of Attapulgite/Cordierite Coating Honeycomb and its Environmental Applications

• Published in: Kinetics and catalysis Vol. 65; no. 3; pp. 298 - 307
• Main Authors: Liu, Wei, Wu, Fengqin, Liu, Jingwei, Meng, Jie, Gao, Bingying, Zuo, Shixiang, Yao, Chao
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 2024; Springer Nature B.V
• Subjects: Catalysis; Catalysts; Catalytic oxidation; Chemistry; Chemistry and Materials Science; Coating; Cordierite; Image enhancement; Nitric acid; Oxidation; Physical Chemistry; Specific surface; Surface area; Toluene; Ultrasonic testing; VOCs; attapulgite; cordierite honeycomb; wash coating
• ISSN: 0023-1584; 1608-3210
• DOI: 10.1134/S0023158423600931

The specific surface area of attapulgite was significantly enhanced (from 128 to 212 m 2 /g) by its purification with sodium hexametaphosphate and nitric acid. Subsequently, an acid modification method was employed to prepare a coated attapulgite cordierite honeycomb with a specific surface area approximately 39 times larger than that of the bare cordierite honeycomb. SEM images showed that the surface of the cordierite was rough and uneven, with the attapulgite filling the large pores on its surface, forming a “nail-like” interaction between the coating and the carrier. After loading the catalyst, no significant mass loss was observed after 1 h of ultrasonic testing, indicating good adhesion stability of the coating. Furthermore, under test conditions of GHSV (Gas Hourly Space Velocity) = 10 000 h –1 and a toluene concentration of 1500 ppm, the prepared integrated catalyst exhibited excellent activity for the catalytic oxidation of toluene, with T 50 and T 90 values of 261 and 290°C, respectively, suggesting broad application prospects.