Microstructure and mechanical properties of Al2O3 ceramic and copper joints brazed with AgCuInTi brazing alloy

• Published in: International journal of applied ceramic technology Vol. 21; no. 6; pp. 4228 - 4240
• Main Authors: Li, Botao, Liu, Ben, Wang, Yong, Hu, Ruoqi, Wang, Ying, Yang, Zhenwen
• Format: Journal Article
• Language: English
• Published: Malden Wiley Subscription Services, Inc 01.11.2024
• Subjects: AgCuInTi brazing alloy; Al2O3 ceramic; Aluminum oxide; Bonded joints; Brazed joints; Brazing alloys; Ceramic bonding; Copper; Mechanical properties; Microstructural analysis; Microstructure; microstructure formation mechanism; Morphology; Process parameters; Shear strength; Silver; Solid solutions; Thickness; Vacuum brazing
• ISSN: 1546-542X; 1744-7402
• DOI: 10.1111/ijac.14828

Reliable metallurgical bonding between Al2O3 ceramic and copper was achieved by vacuum brazing using Ag–23Cu–14.5In–3.3Ti (wt.%) alloy. The representative interfacial structure of the joint was Al2O3/Ti3(Cu,Al)3O + γ‐TiO/Ag‐based solid solution + (Cu,Ag)7In3 + Ag–Cu eutectic + Cu‐based solid solution/copper. The interface microstructure evolved with process parameters, including the formation of γ‐TiO and Ti3(Cu,Al)3O, as evidenced by microstructural analysis and etched surface morphology. The relationship between fracture path and shear strength was established by observing the fracture morphology and performing shear strength tests on joints with various process parameters, utilizing the degree of the Ag‐based solid solution loss and the thickness of the reaction layer as evaluative factors. When brazed at 760 or 780°C for 20 min using a 100 µm brazing alloy foil, the brazed joints demonstrated a peak shear strength of 215 ± 25 MPa, and the fracture predominantly occurred in the Al2O3 matrix and Ti3(Cu,Al)3O layer.