3-Mesityl-2-oxo-1-oxaspiro-[4.4]non-3-en-4-yl 4-chloro-benzoate

The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo-pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 65; no. Pt 4; p. o705
Main Authors Ji, Ming-Hua, Xia, Min, Zhu, Guo-Nian, Zhao, Jin-Hao
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 06.03.2009
Subjects
Organic Papers
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Summary:The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo-pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and 81.9 (2)°, respectively, with the 2,4,6-trimethyl-phenyl and 4-chloro-phenyl rings. The dihedral angle between the two benzene rings is 76.6 (1)°. In the crystal, mol-ecules are linked through weak inter-molecular C-H⋯O hydrogen bonds, forming chains running along the c axis.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809006503