High ionic conduction in a robust anionic metal–organic framework containing Mg2+ under guest vapors

We report on the synthesis and high ionic conductivity of a highly crystalline Mg2+-containing metal–organic framework (MOF) with Type A feature (i.e., anionic framework having Mg2+ as a counter cation). We synthesized Mg[Zr(C14H3O8)2] (SU-102-Mg) through ion exchange reaction. SU-102-Mg showed a hi...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 53; no. 29; pp. 12043 - 12046
Main Authors Niwa, Shintaro, Hashimoto, Shuhei, Chen, Duotian, Toyao, Takashi, Shimizu, Ken-ichi, Sadakiyo, Masaaki
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 23.07.2024
Subjects
Ion currents
Ion exchange
Metal-organic frameworks
Zirconium
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Summary:We report on the synthesis and high ionic conductivity of a highly crystalline Mg2+-containing metal–organic framework (MOF) with Type A feature (i.e., anionic framework having Mg2+ as a counter cation). We synthesized Mg[Zr(C14H3O8)2] (SU-102-Mg) through ion exchange reaction. SU-102-Mg showed a high ionic conductivity of 3.6 × 10−5 S cm−1 (25 °C, under MeCN vapor).
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content type line 23
ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/d4dt01331j