Efficient and selective removal of Pb2+ from aqueous solution by using an O− functionalized metal–organic framework

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 51; no. 26; pp. 10077 - 10084
• Main Authors: Jiang, Wen, Cai-Xia, Yu, Ming-Xuan, Yu, Ding, Jing, Jian-Guo, Song, Xue-Qin, Sun, Lei-Lei, Liu
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 05.07.2022
• Subjects: Adsorbents; Adsorption; Aqueous solutions; Heavy metals; Lead; Metal-organic frameworks; Selectivity; Zeta potential
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d2dt01117d

Lead (Pb) is one of the most widespread and highly toxic heavy metals in the environment. The design and synthesis of adsorbent materials for the selective and efficient removal of Pb2+ from aqueous solution has received much attention. Herein, the ligand 4,4′-azoxydibenzoic acid with the O− group was elaborately selected to construct a novel Pr-based MOF for Pb2+ removal. The as-prepared MOF adsorbents with high stability exhibited ultra-high selectivity for Pb2+, even in the presence of various highly concentrated competitive ions (with the ratios from 1 : 5 to 1 : 50). Also, a high uptake capacity (560.26 mg g−1) can be achieved for the MOF material, due to the availability of sufficient adsorption sites. The strong electrostatic attraction and coordination interaction between the numerous active O− sites on MOF adsorbents and Pb2+ can account for the good adsorption performance for Pb2+, which was systematically verified by zeta potential, FT-IR and XPS studies.