Narrow-band blue emitting nitridomagnesosilicate phosphor Sr8Mg7Si9N22:Eu2+ for phosphor-converted LEDs

We report a novel narrow-band blue emitting phosphor Sr7.92Mg7Si9N22:0.08Eu2+. The crystal structure of Sr8Mg7Si9N22 is composed of corner-sharing and edge-sharing [SiN4] tetrahedra and distorted square-pyramid [MgN5] polyhedra. Under 350 nm excitation, Eu2+ doped Sr8Mg7Si9N22 emits narrow-band blue...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 82; pp. 11598 - 11601
Main Authors Li, Chao, Hong-Wei, Zheng, Heng-Wei, Wei, Su, Jie, Fu-Hui, Liao, Zhen-Yi, Zhang, Xu, Ling, Zu-Pei, Yang, Wang, Xiao-Ming, Jiao, Huan
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 21.10.2018
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Summary:We report a novel narrow-band blue emitting phosphor Sr7.92Mg7Si9N22:0.08Eu2+. The crystal structure of Sr8Mg7Si9N22 is composed of corner-sharing and edge-sharing [SiN4] tetrahedra and distorted square-pyramid [MgN5] polyhedra. Under 350 nm excitation, Eu2+ doped Sr8Mg7Si9N22 emits narrow-band blue light with maximum intensity at 450 nm and a fwhm of 38 nm.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc07218c