Design Strategies for High-Performance NH3–SCO Catalysts: Identifying and Modulating Direct Anchoring Sites for Ag on TiO2

• Published in: Environmental science & technology Vol. 58; no. 34; p. 15343
• Main Authors: Wang, Chunxue, Li, Yuan, Li, Zhao, Meng, Caixia, Ma, Yixing, Sun, Xin, Ning, Ping, Li, Kai, Wang, Fei
• Format: Journal Article
• Language: English
• Published: Easton American Chemical Society 27.08.2024
• Subjects: Ammonia; Catalysts; Catalytic oxidation; Density functional theory; Diesel engines; Fourier transforms; Infrared spectroscopy; Internal combustion engines; Metals; Nanoparticles; Oxidation; Silver; Titanium dioxide
• ISSN: 0013-936X; 1520-5851; 1520-5851
• DOI: 10.1021/acs.est.4c06499

Ammonia (NH3) slip from diesel vehicle aftertreatment systems and internal combustion engines fueled by NH3 or NH3/H2 poses serious environmental problems. Ag-based catalysts are widely used for the selective catalytic oxidation of NH3 to N2 (NH3–SCO), and their performance is greatly dependent on the state of Ag, which is influenced by the anchoring sites on the support. Despite efforts to identify the direct anchoring sites of metal atoms on TiO2, conflicting views persist. Here, we compared the correlation between Ag dispersion and the content of hydroxyl (OH) groups or defects on TiO2 and conducted density functional theory (DFT) calculations, and the results confirmed that the surface OH groups of TiO2 serve as the direct anchoring sites for Ag. By modulating the OH group content through thermal induction, the optimal OH group content on TiO2-800 resulted in more metallic Ag nanoparticles (Ag0 NPs) in larger sizes, leading to the development of an excellent NH3–SCO catalyst. Moreover, in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), kinetic studies, and DFT calculations suggested that more Ag0 NPs in larger sizes on 10Ag/TiO2-800 were conducive to O2 activation and NH3 dissociation. Our findings provide new insights for designing efficient NH3–SCO catalysts, and OH groups as direct anchoring sites could be extended to other metals and supports for the rational design of catalysts.