Heteroarene-Directed Oxidative sp(2) C-H Bond Allylation with Aliphatic Alkenes Catalyzed by an (Electron-Deficient eta(5)-Cyclopentadienyl)rhodium(III) Complex
It has been established that the oxidative sp(2) C-H bond allylation with aliphatic alkenes proceeds under mild conditions by using heteroarenes as directing groups and an (electron-deficient eta(5)-cyclopentadienyl)rhodium(III) complex, [(CpRhCl2)-Rh-E](2), as a precatalyst. In sharp contrast, the...
Saved in:
Published in | Organic letters Vol. 18; no. 12; pp. 2934 - 2937 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
WASHINGTON
Amer Chemical Soc
17.06.2016
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | It has been established that the oxidative sp(2) C-H bond allylation with aliphatic alkenes proceeds under mild conditions by using heteroarenes as directing groups and an (electron-deficient eta(5)-cyclopentadienyl)rhodium(III) complex, [(CpRhCl2)-Rh-E](2), as a precatalyst. In sharp contrast, the use of [Cp*RhCl2](2) instead of [(CpRhCl2)-Rh-E](2) led to a complex mixture of products under the same reaction conditions. |
---|---|
Bibliography: | KAKEN ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1523-7060 1523-7052 |
DOI: | 10.1021/acs.orglett.6b01288 |