Preparation and characterization of Pb(Lu1/2Nb1/2)O3–Pb(In1/2Nb1/2)O3–PbTiO3 ternary ferroelectric ceramics with high phase transition temperatures

• Published in: Journal of the American Ceramic Society Vol. 101; no. 12; pp. 5514 - 5523
• Main Authors: Hu, Duan, Wang, Ke, Wang, Linghang, Zhang, Mao‐Hua, Thong, HaoCheng, Liu, YangBin, Xu, Zhuo, Li, Fei
• Format: Journal Article
• Language: English
• Published: Columbus Wiley Subscription Services, Inc 01.12.2018
• Subjects: Ceramics; Curie temperature; Dielectric properties; Ferroelectric materials; Ferroelectricity; high temperature; Lead titanates; Pb(Lu1/2Nb1/2)O3–Pb(In1/2Nb1/2)O3–PbTiO3; Phase transitions; piezoelectric ceramics; Piezoelectricity; Relaxors; relaxor‐PT; Solid phases; Temperature; Temperature dependence; Transition temperature
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/jace.15813

To explore new relaxor‐PbTiO3 systems for high‐power and high‐temperature electromechanical applications, a ternary ferroelectric ceramic system of Pb(Lu1/2Nb1/2)O3–Pb(In1/2Nb1/2)O3–PbTiO3 (PLN–PIN–PT) have been investigated. The phase structure, dielectric, piezoelectric, and ferroelectric properties of the as‐prepared PLN–PIN–PT ceramics near the morphotropic phase boundary (MPB) were characterized. A high rhombohedral‐tetragonal phase transition temperature TR‐T of 165°C and a high Curie temperature TC of 345°C, together with a good piezoelectric coefficient d33 of 420 pC/N, were obtained in 0.38PLN–0.20PIN–0.42PT ceramics. Furthermore, for (0.8−x)PLN–0.2PIN–xPT ceramics, the temperature‐dependent piezoelectric coefficients, coercive fields and electric‐field‐induced strains were further studied. At 175°C, their coercive fields were found to be above 9.5 kV/cm, which is higher than that of PMN–PT and soft P5H ceramics at room temperature, indicating PLN–PIN–PT ceramics to be one of the promising candidates in piezoelectric applications under high‐driven fields. The results presented here could benefit the development of relaxor‐PbTiO3 with enhanced phase transition temperatures and coercive fields.