Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center

Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)-salicylate complexes through an intramolecular oxo-transfer process.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 45; p. 5644
Main Authors Oh, Na Young, Seo, Mi Sook, Lim, Mi Hee, Consugar, Mark B, Park, Mi Joo, Rohde, Jan-Uwe, Han, Jaehong, Kim, Kwan Mook, Kim, Jinheung, Que, Jr, Lawrence, Nam, Wonwoo
Format Journal Article
LanguageEnglish
Published England 07.12.2005
Subjects
Benzoates - chemistry
Heme - chemistry
Hydroxylation
Iron - chemistry
Models, Molecular
Molecular Structure
Oxidation-Reduction
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Summary:Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)-salicylate complexes through an intramolecular oxo-transfer process.
ISSN:1359-7345
DOI:10.1039/b511302d