The racemate cage. Influence of p(1),n(1) salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid

The occurrence of p(1),n(1) salt when accompanied by substrate self-association can have profound effects on enantiomer separation processes of non-racemic mixtures, impeding the complete recovery of the major enantiomer through formation of an inescapable racemate cage.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 26; p. 2717
Main Authors Rosini, Goffredo, Borzatta, Valerio, Boschi, Francesca, Candido, Gabriele, Marotta, Emanuela, Righi, Paolo
Format Journal Article
LanguageEnglish
Published England 14.07.2007
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Summary:The occurrence of p(1),n(1) salt when accompanied by substrate self-association can have profound effects on enantiomer separation processes of non-racemic mixtures, impeding the complete recovery of the major enantiomer through formation of an inescapable racemate cage.
ISSN:1359-7345
1364-548X
DOI:10.1039/b703506c