Li6Na3Sr14Al11P22O90: an oxo-centered Al3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers

A novel and thermally stable aluminum phosphate Li6Na3Sr14Al11P22O90 (1) has been achieved by using a solid-state molten method, which contains an oxo-centered trinuclear cluster and an anti-Lowenstein's rule Al–O–Al linkage and is constructed from two types of (3,6)-connected kgd layers [Al(Al...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 47; no. 2; pp. 298 - 301
Main Authors Xiao-Ni, Yao, Yi-Gang, Chen, Guo, Yao, Ying-Jie, Jia, Xing-Xing, Jiang, Zhang, Xian-Ming
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2018
Subjects
Aluminum phosphate
Clusters
Thermal stability
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Summary:A novel and thermally stable aluminum phosphate Li6Na3Sr14Al11P22O90 (1) has been achieved by using a solid-state molten method, which contains an oxo-centered trinuclear cluster and an anti-Lowenstein's rule Al–O–Al linkage and is constructed from two types of (3,6)-connected kgd layers [Al(Al3O)(PO4)7]25− and [Al(PO4)2]3−. The good optical transparency in the whole UV range and excellent thermal stability make the title compound a potential optical window material.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt03854b