Spectroscopic and kinetic evidence for redox cycling, catalase and degradation activities of Mn(III)(TPPS) in a basic aqueous peroxide medium
Mn(III)(TPPS) was found to react rapidly with hydrogen peroxide in basic aqueous solution to form intermediate (TPPS)Mn(V)[double bond, length as m-dash]O and (TPPS)Mn(IV)[double bond, length as m-dash]O species which, in the presence of excess H2O2, are reduced fully back to Mn(III)(TPPS) with clea...
Saved in:
Published in | Chemical communications (Cambridge, England) Vol. 52; no. 30; pp. 5297 - 5300 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
England
18.04.2016
|
Online Access | Get full text |
Cover
Loading…
Summary: | Mn(III)(TPPS) was found to react rapidly with hydrogen peroxide in basic aqueous solution to form intermediate (TPPS)Mn(V)[double bond, length as m-dash]O and (TPPS)Mn(IV)[double bond, length as m-dash]O species which, in the presence of excess H2O2, are reduced fully back to Mn(III)(TPPS) with clear evidence for redox cycling of Mn(III)(TPPS). The system shows very strong catalase and degradation activities. |
---|---|
Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1364-548X |
DOI: | 10.1039/c6cc01437b |