A Sn(IV)-porphyrin-based metal-organic framework for the selective photo-oxygenation of phenol and sulfides

A functional tin(IV)-porphyrin derivative was used as a building block to construct a novel 3D porous metal-organic framework (MOF). The MOF is built up from tin(IV)-porphyrin struts linking up Zn atoms and formates joining Sn(IV) centers. The immobilization of the photoactive Sn-porphyrins in the c...

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Published inInorganic chemistry Vol. 50; no. 12; pp. 5318 - 5320
Main Authors Xie, Ming-Hua, Yang, Xiu-Li, Zou, Chao, Wu, Chuan-De
Format Journal Article
LanguageEnglish
Published United States 20.06.2011
Subjects
Catalysis
Metalloporphyrins - chemistry
Models, Molecular
Molecular Structure
Oxygen - chemistry
Phenols - chemistry
Photochemistry
Porosity
Stereoisomerism
Sulfides - chemistry
Surface Properties
Tin - chemistry
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Summary:A functional tin(IV)-porphyrin derivative was used as a building block to construct a novel 3D porous metal-organic framework (MOF). The MOF is built up from tin(IV)-porphyrin struts linking up Zn atoms and formates joining Sn(IV) centers. The immobilization of the photoactive Sn-porphyrins in the channel walls lets the MOF present remarkable photocatalytic activities for the oxygenation of phenol and sulfides, resulting in excellent yields and remarkable selectivity in heterogeneous phases.
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ISSN:1520-510X
DOI:10.1021/ic200295h