Reactions of bis(iminophosphosphoranyl) methanes with chloro-bridged rhodium of iridium dimers giving complexes in which the ligand is coordinated either as a σ-N,σ-N' or as a σ-N,σ-C chelate. X-ray crystal structure of the σ-N,σ-N' Rh(I) complex [Rh{4-CH3-C6H4-N=PPh22CH2}(COD)]PF6

• Published in: Inorganica chimica acta Vol. 184; no. 1; pp. 73 - 87
• Main Authors: IMHOFF, P, VAN ASSELT, R, ELSEVIER, C. J, ZOUTBERG, M. C, STAM, C. H
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier Science 01.06.1991
• Subjects: Chemistry; Condensed matter: structure, mechanical and thermal properties; Coordination compounds; Exact sciences and technology; Inorganic chemistry and origins of life; Inorganic compounds; Metal complexes; Physics; Preparations and properties; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Cationic complex; Molecular structure; Organic ligand; Transition metal Complexes; Dienic compound; Experimental study; X ray diffraction; Phosphorus Organic compounds; Complexes Mixed; Preparation; Rhodium I Complexes; Platinoid Complexes; Monocyclic compound; Univalent metal Complexes; Crystalline structure
• ISSN: 0020-1693; 1873-3255
• DOI: 10.1016/S0020-1693(00)83048-0