Sparsely substituted chlorins as core constructs in chlorophyll analogue chemistry. II. Derivatization

Stable chlorins bearing few or no substituents have been subjected to a variety of reactions including demetalation, magnesium insertion, oxochlorin formation, and bromination followed by Suzuki coupling. The kinetics of deuteration also have been determined for two oxochlorins and a series of chlor...

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Published inTetrahedron Vol. 63; no. 18; pp. 3840 - 3849
Main Authors Taniguchi, Masahiko, Ptaszek, Marcin, McDowell, Brian E, Lindsey, Jonathan S
Format Journal Article
LanguageEnglish
Published England 30.04.2007
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Summary:Stable chlorins bearing few or no substituents have been subjected to a variety of reactions including demetalation, magnesium insertion, oxochlorin formation, and bromination followed by Suzuki coupling. The kinetics of deuteration also have been determined for two oxochlorins and a series of chlorins bearing 0, 1, 2, or 3 meso-aryl substituents.
Bibliography:ObjectType-Article-1
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Corresponding author. Tel.: +19195156406; fax +19195132830; e-mail: jlindsey@ncsu.edu
ISSN:0040-4020
DOI:10.1016/j.tet.2007.02.076