X-ray structure analysis of symmetrically substituted 1,1'-diformyl-ruthenocene

1,1'-Di-formyl-ruthenocene, [Ru(C H O) ], crystallizes in the ortho-rhom-bic system in the 2 2 2 space group at room temperature. There are two crystallographically independent mol-ecules in the asymmetric unit. The cyclo-penta-dienyl rings have eclipsed configuration. The mol-ecules self-assem...

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Bibliographic Details
Published inActa crystallographica. Section E, Crystallographic communications Vol. 74; no. Pt 9; pp. 1186 - 1189
Main Authors Anzaldo, Bertin, Sharma, Pankaj, Lara Ochoa, Francisco, Villamizar C, Claudia P, Gutiérrez Pérez, René
Format Journal Article
LanguageEnglish
Published England International Union of Crystallography 01.09.2018
Subjects
Research Communications
crystal structure
1,1′-di­formyl­ruthenocene
ruthenocene
X-ray structure
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Summary:1,1'-Di-formyl-ruthenocene, [Ru(C H O) ], crystallizes in the ortho-rhom-bic system in the 2 2 2 space group at room temperature. There are two crystallographically independent mol-ecules in the asymmetric unit. The cyclo-penta-dienyl rings have eclipsed configuration. The mol-ecules self-assemble in a two-dimensional structure by C-H⋯O and C-H⋯π inter-actions with relative orientations of the two formyl groups. The crystal studied was refined as an inversion twin.
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ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989018010642