2,5-Bis{[(-)-(S)-1-(4-methyl-phen-yl)eth-yl]imino-meth-yl}thio-phene
The title chiral bis-aldimine, C24H26N2S, was synthesized using a solvent-free Schiff condensation. The mol-ecule displays crystallographic C 2 symmetry, with the S atom lying on the twofold axis parallel to [100]. As a consequence of the (S,S) stereochemistry, the tolyl groups are oriented towards...
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Published in | Acta crystallographica. Section E, Structure reports online Vol. 69; no. Pt 9; p. o1428 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
United States
International Union of Crystallography
2013
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Subjects | |
Online Access | Get full text |
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Summary: | The title chiral bis-aldimine, C24H26N2S, was synthesized using a solvent-free Schiff condensation. The mol-ecule displays crystallographic C 2 symmetry, with the S atom lying on the twofold axis parallel to [100]. As a consequence of the (S,S) stereochemistry, the tolyl groups are oriented towards opposite faces of the thiophene core, giving a twisted conformation for the whole mol-ecule. Mol-ecules are arranged in the crystal in a herringbone-like pattern, without any significant inter-molecular contacts. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536813021685 |