Synthesis of Polystyrene and Poly(4‐vinylpyridine) Mixed Grafted Silica Nanoparticles via a Combination of ATRP and CuI‐Catalyzed Azide‐Alkyne Click Chemistry

• Published in: Macromolecular rapid communications. Vol. 38; no. 1
• Main Authors: Wu, Lei, Glebe, Ulrich, Böker, Alexander
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.01.2017
• Subjects: binary polymer brushes; grafting‐to method; Huisgen cycloaddition; post‐ATRP modification; pre‐ATRP modification
• ISSN: 1022-1336; 1521-3927
• DOI: 10.1002/marc.201600475

Binary polystyrene and poly(4‐vinylpyridine) mixed grafted silica nanoparticles (PSt/P4VP‐g‐SNPs) are fabricated using CuI‐catalyzed azide‐alkyne Huisgen cycloaddition (CuAAC) via grafting‐to method. Azide‐terminated PSt and P4VP are synthesized via post‐ and pre‐atom transfer radical polymerization modification, respectively. Then, the polymers are simultaneously anchored onto alkyne‐modified SNPs by CuAAC yielding mixed brushes as shown by Raman spectroscopy, dynamic light scattering, and thermogravimetric analysis. To the best of our knowledge, this is the first report of simultaneously grafting two distinct polymer chains to synthesize mixed grafted silica nanoparticles using CuAAC technique via grafting‐to method. Facile synthesis of polystyrene (PSt) and poly(4‐vinylpyridine) (P4VP) mixed grafted silica nanoparticles using CuI‐catalyzed azide‐alkyne Huisgen cycloaddition (CuAAC) via grafting‐to method is reported. Post‐ and pre‐ATRP modification approaches are utilized to synthesize azide‐terminated PSt and P4VP, respectively. Afterward, the two polymers with different molecular weights are simultaneously grafted onto alkyne‐functionalized silica nanoparticles by CuAAC yielding mixed brushes.