Crystal structure of hexa-kis-(dimethyl sulfoxide-κO)manganese(II) diiodide

The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(-) counter-anions. The isolated complex cations have an octa-hedral configuration and are grouped in hexa-gonally arranged rows extending parallel to [100]. The...

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Bibliographic Details
Published inActa crystallographica. Section E, Crystallographic communications Vol. 72; no. Pt 7; pp. 904 - 906
Main Authors Glatz, Mathias, Schroffenegger, Martina, Weil, Matthias, Kirchner, Karl
Format Journal Article
LanguageEnglish
Published England International Union of Crystallography 01.07.2016
Subjects
Research Communications
crystal structure
manganese(II)
dimethyl sulfoxide
octa­hedral coordination
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Summary:The asymmetric unit of the title salt, [Mn(C2H6OS)6]I2, consists of one Mn(II) ion, six O-bound dimethyl sulfoxide (DMSO) ligands and two I(-) counter-anions. The isolated complex cations have an octa-hedral configuration and are grouped in hexa-gonally arranged rows extending parallel to [100]. The two I(-) anions are located between the rows and are linked to the cations through two weak C-H⋯I inter-actions.
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ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989016008896