A Heterobimetallic AuIII‐PtII Photocatalyst for Water Reduction to Hydrogen

A supramolecular complex, [Au(C^N^C)(C≡CC6H4C≡C)Pt(terpy)]+, has been synthesized as a photocatalyst for water reduction. This compound consists of a cyclometalated alkyne‐gold(III) photosensitizer and a platinum(II) terpyridine complex bridged through a central phenylethynyl group. Au Ptit Bistrot:...

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Published inChemistry, an Asian journal Vol. 14; no. 4; pp. 527 - 531
Main Authors Su, Yi‐Bing, Yuan, Yong‐Jun, Liu, Xiao‐Le, Chen, Guang‐Hui, Chen, Xin, Yu, Zhen‐Tao, Zou, Zhi‐Gang
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 15.02.2019
Subjects
Alkynes
Chemistry
density functional calculations
Gold
heterobimetallic system
hydrogen evolution
photocatalysis
Photocatalysts
Platinum
Reduction
supramolecular chemistry
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Summary:A supramolecular complex, [Au(C^N^C)(C≡CC6H4C≡C)Pt(terpy)]+, has been synthesized as a photocatalyst for water reduction. This compound consists of a cyclometalated alkyne‐gold(III) photosensitizer and a platinum(II) terpyridine complex bridged through a central phenylethynyl group. Au Ptit Bistrot: A heterobimetallic AuIII‐PtII complex has been synthesized and evaluated as photocatalyst for water reduction.
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ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201801591