Chlorido{5,10,15,20-tetra-kis-[2-(2,2-dimethyl-propanamido)-phen-yl]porphyrinato-κN,N',N'',N'''}iron(III) chloro-benzene hemisolvate monohydrate

• Published in: Acta crystallographica. Section E, Structure reports online Vol. 67; no. Pt 4; pp. m460 - m461
• Main Authors: Dhifet, Mondher, Belkhiria, Mohamed Salah, Daran, Jean-Claude, Nasri, Habib
• Format: Journal Article
• Language: English
• Published: United States International Union of Crystallography 01.04.2011
• Subjects: Metal-Organic Papers
• ISSN: 1600-5368
• DOI: 10.1107/S1600536811009299

In the title complex, [Fe(C(64)H(64)N(8)O(4))Cl]·0.5C(6)H(5)Cl·H(2)O, the equatorial iron-pyrrole N atom distance (Fe-N(p)) is 2.065 (2) Å and the axial Fe-Cl distance is 2.207 (2) Å. The iron cation is displaced by 0.420 (4) Å from the 24-atom mean plane of the porphyrin core. The asymmetric unit contains a quarter of an [Fe(III)(C(64)H(64)N(8)O(4))Cl] complex mol-ecule, with a fourfold rotation axis passing through the central metal cation and the Cl ligand, along with disordered mol-ecules of chloro-benzene and water of solvation; the solvent mol-ecules were excluded from the refinement.