Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd3Bi7 and Sm3Bi7

The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corres...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 51; pp. 7089 - 7092
Main Authors Ovchinnikov, Alexander, Makongo, Julien P A, Bobev, Svilen
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2018
Subjects
Crystal structure
Electronic structure
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
MATERIALS SCIENCE
Phase diagrams
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Summary:The binary bismuthides Nd3Bi7 and Sm3Bi7 were synthesized and structurally characterized for the first time. The results from the calorimetric analysis show that both compounds are stable only up to about 500 °C, which may explain why they were overlooked during the original assessment of the corresponding phase diagrams.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
SC0008885
USDOE Office of Science (SC), Basic Energy Sciences (BES)
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc02563k