In2O3-based micro gas sensor for detecting NOx gases

• Published in: Electronic materials letters Vol. 10; no. 2; pp. 509 - 513
• Main Authors: Kim, Bum-Joon, Song, In-Gyu, Kim, Jung-Sik
• Format: Journal Article
• Language: English
• Published: Springer The Korean Institute of Metals and Materials 01.03.2014; 대한금속·재료학회
• Subjects: Characterization and Evaluation of Materials; Chemistry and Materials Science; Condensed Matter Physics; Materials Science; Nanotechnology; Nanotechnology and Microengineering; Optical and Electronic Materials; 전자/정보통신공학; indium oxide; MEMS; micro gas sensor; sol-gel process; nitrogen oxides
• ISSN: 1738-8090; 2093-6788
• DOI: 10.1007/s13391-013-3133-z

In this study, NO x micro gas sensors for monitoring the indoor atmosphere of automobile were fabricated using MEMS (microelectromechanical system) technology and a sol-gel process. The sensing electrode and micro heater were designed to have a co-planar typed structure in a Pt thin film layer. The thermal characteristics of a micro heater array were analyzed using a finite element method (FEM). The chip size of the gas sensor was approximately 2 mm × 2 mm. Indium oxide as a sensing material for NO x gas was synthesized by a sol-gel process with indium isopropoxide as a precursor. Field emission Scanning electron microscopy and x-ray diffraction showed that particle size of the synthesized In 2 O 3 was approximately 17–45 nm. The maximum gas sensitivity as the relative resistance ( R s = R gas / R air ) was observed at 275°C with a value of 8.0 at 1 ppm NO 2 gas. The response (80% saturation) and recovery times were within 1 min. The sensing properties of NO 2 gas exhibited linear behavior with increasing gas concentration. The sensing mechanism of the gas sensor was explained by the variations in the electron depletion layers and the adsorption of gas molecules on the In 2 O 3 particle surface. These results suggest that in the future, MEMS-based gas sensors can be used as automotive-exhaust-gas sensors.