Energy Band Structure and Photocatalytic Property of Fe-doped Zn2TiO4 Material

• Published in: Bulletin of the Korean Chemical Society pp. 3021 - 3024
• Main Authors: 장점석, Pramod H. Borse, 이재성, 임권택, 정옥상, 정의덕, Jong Seong Bae, 원미숙, 김현규
• Format: Journal Article
• Language: English
• Published: 대한화학회 01.12.2009
• Subjects: 화학
• ISSN: 0253-2964; 1229-5949
• DOI: 10.5012/bkcs.2009.30.12.3021

Zn2Ti1-xFexO4 (0 ≤ x ≤ 0.7) photocatalysts were synthesized by polymerized complex (PC) method and investigated for its physico-chemical as well as optical properties. Zn2Ti1-xFexO4 can absorb not only UV light but also visible light region due to doping of Fe in the Ti site of Zn2TiO4 lattice because of the band transition from Fe 3d to the Fe 3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped Zn2TiO4 samples for hydrogen product ion under UV light irradiation decreased with an increase in Fe concentration in Zn2TiO4. Consequently, there exists an optimized concentration of iron for improved photocatalytic activity under visible light (λ ≥ 420 nm) Zn2Ti1-xFexO4 (0 ≤ x ≤ 0.7) photocatalysts were synthesized by polymerized complex (PC) method and investigated for its physico-chemical as well as optical properties. Zn2Ti1-xFexO4 can absorb not only UV light but also visible light region due to doping of Fe in the Ti site of Zn2TiO4 lattice because of the band transition from Fe 3d to the Fe 3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped Zn2TiO4 samples for hydrogen production under UV light irradiation decreased with an increase in Fe concentration in Zn2TiO4. Consequently, there exists an optimized concentration of iron for improved photocatalytic activity under visible light (λ ≥ 420 nm) KCI Citation Count: 29