가성소다(NaOH) 용액을 이용한 선상 이산화탄소 포집 장치의 선박 검증시험

• Published in: 大韓造船學會 論文集 Vol. 61; no. 1; pp. 51 - 60
• Main Authors: 이광현(Gwang Hyun Lee), 노형주(Hyung Ju Roh), 이민우(Min woo Lee), 손원경(Won Kyeong Son), 정재열(Jae Yeoul Jeong), 김태홍(Tae-Hong Kim), 남병탁(Byung-Tak NAM), 김재익(Jae-Ik Kim)
• Format: Journal Article
• Language: Korean
• Published: 대한조선학회 2024
• Subjects: 조선공학; Carbonic Acid(H2CO3; 선상 이산화탄소 포집장치; 가성소다; 산화칼슘; 탄산; Sodium hydroxide(NaOH; Calcium Carbonate(CaCO3; Calcium Oxide(CaO; 탄산칼슘; Onboard Carbon dioxide Capture System(OCCS
• ISSN: 1225-1143; 2287-7355
• DOI: 10.3744/SNAK.2024.61.1.51

Hi Air Korea and Hanwha ocean are currently developing an Onboard Carbon dioxide Capture System (OCCS) to absorb CO2 emitted from ship's engine using a sodium hydroxide(NaOH) solution, and converting the resulting salt into a solid form through a chemical reaction with calcium oxide (CaO). The system process involves the following steps; 1)The reaction of CO2 gas absorption in water, 2)The reaction between carbonic acid (H2CO3) and NaOH solution to produce carbonate or bicarbonate, and 3)The reaction between carbonate or bicarbonate and CaO to form calcium carbonate (CaCO3). And ultimately, the solid material, CaCO3, is separated and discharged using a separator. The OCCS has been installed on an ship and the test results have confirmed significant reduction effects of CO2 in the ship's exhaust gas. A portion of the exhaust gas emitted from the engine was transferred to the OCCS using a blower. The flow rate of the transferred gas ranged from 800 to 1384 m3/hr, and the CO2 concentration in the exhaust gas was 5.1 vol% for VLSFO, 3.7 vol% for LNG and a 12 wt% NaOH solution was used. The results showed a CO2 capture efficiency of approximately 42.5 to 64.1 vol% and the CO2 capture rate approximately 48.4 to 52.2kg/hr. Additionally, to assess the impact of the discharged CaCO3on the marine ecosystem, we conducted "marine ecotoxicity test" and performed Computational Fluid Dynamics (CFD) analysis to evaluate the dispersion and dilution of the discharged effluent.