KOH 농도 및 탄화온도가 왕겨 활성 바이오차의 NH 4 -N 흡착능 향상에 미치는 영향

• Published in: Hanguk hwangyeong nonghak hoeji Vol. 39; no. 3; pp. 171 - 177
• Main Authors: 김희선, Huiseon Kim, 윤석인, Seok-in Yun, 안난희, Nanhee An, 신중두, Joungdu Shin
• Format: Journal Article
• Language: Korean
• Published: 한국환경농학회 30.09.2020
• Subjects: Absorption capacity; Rice hull activated biochar; Absorption capacity; Rice hull activated biochar
• ISSN: 1225-3537; 2233-4173

BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH 4 -N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g -1 , and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g -1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g -1 . The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH 4 -N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (R L ) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (q m ) and the bond strength constants (b) were 0.092 mg g -1 and 0.001 mg L -1 , respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.