Functional Coordination Polymers and Metal–Organic Frameworks

• Format: eBook
• Language: English
• Published: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute 2021
• Subjects: 1H-indazole-6-carboxylic acid; 3-bis; 4-triazol-4-yl)adamantane; 4′-bipyridine; adsorption; adsorption heat pump; Ag(I) complexes; cadmium; calorimetry; carbon dioxide; catalysis; cerium; coordination bonds; coordination polymer; coordination polymers; copper; crystal structure; Cu(II)-4; dimensionality control; dipyridil ligand; ethanol adsorption; gas separation; gas storage; group 12 metals; iridium catalysis; luminescence; metal-organic coordination polymers; metal–organic framework; metal–organic frameworks; MOF; n/a; organometallic; phosphorescence; photoluminescence properties; poly(azolate) spacers; porous materials; post-synthetic modification; pyrimidylphosphines; Reference, Information and Interdisciplinary subjects; Research and information: general; shaping; solid sorbents; spectroscopic characterization; supramolecular chemistry; terephthalic acid; thermally activated delayed fluorescence; thiadiazole; thiazole; water adsorption; water harvesting; water oxidation; water splitting; zinc; zirconium; zirconium-based MOFs
• ISBN: 3036514996; 9783036514994; 3036515003; 9783036515007
• DOI: 10.3390/books978-3-0365-1499-4

This book is a collection of contributions on the synthesis, characterization, and applications of Metal-Organic Frameworks (MOF) and Coordination Polymers (CP). Coordination Polymers (CP) and Metal–Organic Frameworks (MOF) are at the core of contemporary research on inorganic materials. The virtually infinite combination of their building blocks—inorganic metallic nodes (single ions or clusters) and organic polytopic linkers (polycarboxylates, bridging N-/S-/O-containing heterocycles)—generates solid air- and water-stable compounds. Interesting features from an applicative point of view are porosity, large surface area, and lattice flexibility (the “breathing” effect). These properties make them ubiquitous in several fields of materials science: gas storage and separation, luminescent sensing, heterogeneous catalysis, and magnetism.