A Highly Selective Potentiometric Sensor of Molybdate Based on a μ-Oxo-bridged Manganeseporphyrin Dimer

• Published in: Analytical Sciences Vol. 22; no. 7; pp. 949 - 953
• Main Authors: FANG, Zheng-Hui, HAN, Zhi-Xiang, ZHANG, Xiao-Bing, SHEN, Guo-Li, YU, Ru-Qin
• Format: Journal Article
• Language: English
• Published: Japan The Japan Society for Analytical Chemistry 2006
• Subjects: Dimerization; Electrodes; Hydrogen-Ion Concentration; Ion-Selective Electrodes; Manganese - chemistry; Manganese Compounds - analysis; Membranes, Artificial; Metalloporphyrins - chemistry; Molybdenum - chemistry; Oxides - analysis; Polyvinyl Chloride - chemistry; Potentiometry - methods; Solvents - chemistry
• ISSN: 0910-6340; 1348-2246
• DOI: 10.2116/analsci.22.949

A novel high-selective potentiometric sensor for molybdate was prepared with a PVC membrane combining μ-oxo-bis[5,10,15,20-tetra(p-methylphenyl)porphinatomanganese(III)] [[Mn(p-Me)TPP]2O] as an electroactive material and 2-nitrophenyl octyl ether (o-NPOE) as a plasticizer in the percentage ratio of 3:65:32, [Mn(p-Me)TPP]2O:o-NPOE:PVC (w:w). The sensor exhibited a linear response with a Nernstian slope of 30.5 mV per decade within a concentration range of 2.1 × 10-6 to 1.0 × 10-1 M MoO42-, with a working pH range from 5.0 to 12.5, and a fast response time of less than 15 s. The electrode showed improved selectivity toward molybdate with respect to common coexisting anions compared to monometalloporphyrin counterparts. Several electroactive materials and solvent mediators were compared and the experimental conditions were optimized. The sensor is preliminary applied to the assay of MoO42- in corrosion inhibitor samples with satisfactory results.