Nanoscale symmetry fluctuations in ferroelectric barium titanate, BaTiO3
Crystal charge density is a ground-state electronic property. In ferroelectrics, charge is strongly influenced by lattice and vice versa, leading to a range of interesting temperature-dependent physical properties. However, experimental determination of charge in ferroelectrics is challenging becaus...
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Published in | Acta crystallographica. Section B, Structural science Vol. 73; no. 4; p. 708 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Malden
Blackwell Publishing Ltd
01.08.2017
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Subjects | |
Online Access | Get full text |
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Summary: | Crystal charge density is a ground-state electronic property. In ferroelectrics, charge is strongly influenced by lattice and vice versa, leading to a range of interesting temperature-dependent physical properties. However, experimental determination of charge in ferroelectrics is challenging because of the formation of ferroelectric domains. Demonstrated here is the scanning convergent-beam electron diffraction (SCBED) technique that can be simultaneously used for imaging ferroelectric domains and identifying crystal symmetry and its fluctuations. Results from SCBED confirm the acentric tetragonal, orthorhombic and rhombohedral symmetry for the ferroelectric phases of BaTiO3. However, the symmetry is not homogeneous; regions of a few tens of nanometres retaining almost perfect symmetry are interspersed in regions of lower symmetry. While the observed highest symmetry is consistent with the displacive model of ferroelectric phase transitions in BaTiO3, the observed nanoscale symmetry fluctuations are consistent with the predictions of the order-disorder phase-transition mechanism. |
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ISSN: | 2052-5192 2052-5206 |
DOI: | 10.1107/S2052520617008496 |