Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N2O2- and N2O4-type dipyrrins

The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N2O2/N2O4-type dipyrrins were synthesized and characterized. The N2O2-type complexes showed efficient luminescent properties even in polar solvents. The N2O4-type complexes exhibited fluorometric responses to alkaline e...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 48; no. 35; pp. 13169 - 13175
Main Authors Sumiyoshi, Akinobu, Chiba, Yusuke, Matsuoka, Ryota, Noda, Takumu, Nabeshima, Tatsuya
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 2019
Subjects
Alkaline earth metals
Crystallography
Emission spectra
Fluorescence
Gallium
Nitrogen tetroxide
NMR
Nuclear magnetic resonance
Optical properties
Titration
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Summary:The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N2O2/N2O4-type dipyrrins were synthesized and characterized. The N2O2-type complexes showed efficient luminescent properties even in polar solvents. The N2O4-type complexes exhibited fluorometric responses to alkaline earth metal ions.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt02403d