Comparison between DySc2N@C80 and Dy2ScN@C80 single-molecule magnetic metallofullerenes encapsulated in single-wall carbon nanotubes

Encapsulation of a metallofullerene single-molecule magnet, Dy2ScN@C80, into single-wall carbon nanotubes (SWCNTs) accelerates magnetic relaxation processes. In contrast, encapsulation of DySc2N@C80 suppresses them. The effects of the encapsulation are discussed in terms of intermolecular magnetic i...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 51; no. 16; pp. 6339 - 6344
Main Authors Ito, Satoshi, Nakanishi, Ryo, Katoh, Keiichi, Breedlove, Brian K, Sato, Tetsu, Zhao-Yang, Li, Horii, Yoji, Wakizaka, Masanori, Yamashita, Masahiro
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 20.04.2022
Subjects
Charge transfer
Encapsulation
Magnetic induction
Magnetic relaxation
Metallofullerenes
Single wall carbon nanotubes
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Summary:Encapsulation of a metallofullerene single-molecule magnet, Dy2ScN@C80, into single-wall carbon nanotubes (SWCNTs) accelerates magnetic relaxation processes. In contrast, encapsulation of DySc2N@C80 suppresses them. The effects of the encapsulation are discussed in terms of intermolecular magnetic interactions and charge transfer among metallofullerenes and SWCNTs.
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ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/d2dt00524g