Platinum Supported on NbRuyOz as Electrocatalyst for Ethanol Oxidation in Acid and Alkaline Fuel Cells

• Published in: Journal of physical chemistry. C Vol. 115; no. 7
• Main Authors: Kotaro, S., Konopka, D.A., Li, M., Artyushkova, K., Marinkovic, N., Adzic, R., Ward, T.L., Atanassov, P.
• Format: Journal Article
• Language: English
• Published: United States 24.02.2011
• Subjects: 30 DIRECT ENERGY CONVERSION; CHLORIDES; DEPOSITION; DISTRIBUTION; ELECTROCATALYSTS; ETHANOL; FUEL CELLS; IMPREGNATION; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MORPHOLOGY; OXIDATION; PLATINUM; PRECURSOR; PYROLYSIS; VALENCE; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY
• ISSN: 1932-7447; 1932-7455
• DOI: 10.1021/jp109239c

Platinum supported on a mixed metal oxide, NbRu{sub y}O{sub z} (8Nb:1Ru), was evaluated as an electrocatalyst for the ethanol oxidation reaction (EOR) in 0.1 M HClO{sub 4} and 1 M KOH. The support was synthesized from a liquid precursor solution of metal chlorides that was aerosolized and thermally decomposed into a powder via the spray pyrolysis (SP) process. Two samples were of primary interest: 30%Pt deposited onto the support by dry impregnation and 60%Pt as part of the precursor solution that underwent in situ SP Pt dispersion. TEM, SEM, and XRD were used to confirm morphology and deposition of Pt. XPS and XAS studies confirmed elemental distribution and oxidation state of Pt catalyst. In situ IRRAS studies in 0.1 M HClO{sub 4} show that these electrocatalysts are capable of facilitating the complete oxidation pathway of EOR, involving scission of the C-C bond and CO oxidation.