塩基性溶融塩を用いたポリ塩化ビフェニルの分解プロセス

• Published in: 鉄と鋼 Vol. 100; no. 6; pp. 809 - 815
• Main Authors: 四日, 康文, 木村, 賢宜, 半田, 岳士, 佐々木, 光平, 竹田, 修, 山村, 力, 佐藤, 讓
• Format: Journal Article
• Language: Japanese
• Published: 一般社団法人 日本鉄鋼協会 2014
• Subjects: basic molten salts; decomposition; PCB; waste treatment
• ISSN: 0021-1575; 1883-2954
• DOI: 10.2355/tetsutohagane.100.809

The decomposition of polychlorobiphenyls (PCBs) by means of basic molten salts was investigated in order to construct a safe, simple andhighly efficient waste treatment system for PCBs. PCBs (mono, di, tri, tetra, penta, hexa, hepta-chlorobiphenyls) solution was injected intobasic molten salts (KOH-K2CO3 or NaOH-Na2CO3) at 773~973 K with oxygen or imitation air. The mass of residual PCBs in the exhaust afterthe decomposition and the mass of PCBs condensed inside the reaction vessel were measured by using gas chromatograph mass spectrometry,and the decomposition efficiency of PCBs was determined. The decomposition efficiency was also determined from the residual concentrationof PCBs in the exhaust in some experiments. The decomposition efficiency was high regardless of the number of chlorine contained in PCBsand reached to very high of 99.999% in an optimum condition. Chlorine of PCBs was captured in basic molten salts, and organic compoundscontaining chlorine was not emitted from the molten salts. Some by-products comprising benzene rings were found at 773~873 K, but the byproductsdisappeared at 973 K.