Partitioning of Solute Elements and Microstructural Changes during Heat-treatment of Cold-rolled High Strength Steel with Composite Microstructure

• Published in: Tetsu-to-Hagane Vol. 108; no. 1; pp. 41 - 53
• Main Authors: Nakagaito, Tatsuya, Yamashita, Takako, Funakawa, Yoshimasa, Kajihara, Masanori
• Format: Journal Article
• Language: Japanese
• Published: The Iron and Steel Institute of Japan 2022
• Subjects: dual phase; ferrite transformation; intercritical annealing; local equilibrium; paraequilibrium; partitioning; phase diagram; phase transformation; reverse transformation; thermodynamics; TRIP
• ISSN: 0021-1575; 1883-2954
• DOI: 10.2355/tetsutohagane.TETSU-2021-088

The partitioning of solute elements during intercritical annealing and the effects of partitioning on ferrite transformation during slow cooling after intercritical annealing in a 0.17% C-1.5% Si-1.7% Mn (mass%) steel were investigated by a new FE-EPMA (field emission electron probe microanalysis) technique. This new technique enables highly accurate measurement of the C distribution. During the intercritical annealing, C and Mn concentrated into austenite, while Si concentrated into ferrite. The distribution of Mn in austenite was inhomogeneous, and austenite with small Mn content was transformed into ferrite during slow cooling. This ferrite transformation proceeded in the NPLE (negligible partitioning local equilibrium) mode. Two kinds of ferrite were produced due to slow cooling, one being intercritically-annealed ferrite, and the other transformed ferrite. The transformed ferrite had larger Mn content than the intercritically-annealed ferrite. Furthermore, the transformed ferrite was classified into the ferrite grown epitaxially from the intercritically-annealed ferrite and that nucleated in the austenite with relatively small Mn content. Prior microstructure and distribution of solute elements before cooling are determined by the intercritical annealing conditions, and then control the ferrite transformation. Precise control of the ferrite transformation is effective for stable production of cold-rolled high strength steel with composite microstructure.