Molybdate templated assembly of Ln12Mo4-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core

Three heterometallic cluster complexes {Ln(12)Mo(4)} featuring an Ln(12) core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO(4)(2-) anions as ancillary ligands. Magnetic studies of the {Gd(12)Mo(4)} cluster revealed a large magnetocaloric effect due to the pres...

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Published inChemical communications (Cambridge, England) Vol. 49; no. 1; pp. 36 - 38
Main Authors Zheng, Yong, Zhang, Qian-Chong, Long, La-Sheng, Huang, Rong-Bin, Müller, Achim, Schnack, Jürgen, Zheng, Lan-Sun, Zheng, Zhiping
Format Journal Article
LanguageEnglish
Published England 04.01.2013
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Summary:Three heterometallic cluster complexes {Ln(12)Mo(4)} featuring an Ln(12) core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO(4)(2-) anions as ancillary ligands. Magnetic studies of the {Gd(12)Mo(4)} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(III) ions.
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ISSN:1364-548X
DOI:10.1039/c2cc36530h