Diverse catalytic reactivity of a dearomatized PN3P–nickel hydride pincer complex towards CO2 reduction

A dearomatized PN3P*–nickel hydride complex has been prepared using an oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selective methylation and formylation of amines with CO2 were demonstrated by such...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 54; no. 81; pp. 11395 - 11398
Main Authors Li, Huaifeng, Gonçalves, Théo P, Zhao, Qianyi, Gong, Dirong, Lai, Zhiping, Wang, Zhixiang, Zheng, Junrong, Kuo-Wei, Huang
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 09.10.2018
Subjects
Amines
Carbon dioxide
Catalysis
Crystallography
Hydrides
Hydrosilylation
methanol
Methylation
Nickel
NMR
Nuclear magnetic resonance
Reduction
Online AccessGet full text

Cover

More Information
Summary:A dearomatized PN3P*–nickel hydride complex has been prepared using an oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selective methylation and formylation of amines with CO2 were demonstrated by such a PN3P*–nickel hydride complex, highlighting its versatile functions in CO2 reduction.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 14
content type line 23
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c8cc05948a