ChemInform Abstract: Synthesis of Functionalized CF3-Containing Heterocycles via [2,3]-Sigmatropic Rearrangement and Sequential Catalytic Carbocyclization

Copper‐catalyzed tandem ylide formation—[2,3]‐sigmatropic rearrangement of CF3‐containing diazo compounds (II) with amines and sulfides containing two allyl and/or propargyl groups, e.g. (I), (V), (IX) or (XIII), affords the corresponding dienes, enynes or allenynes.

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Bibliographic Details
Published inChemInform Vol. 42; no. 39; p. no
Main Authors Vorobyeva, Daria V., Mailyan, Artur K., Peregudov, Alexander S., Karimova, Natalia M., Vasilyeva, Tamara P., Bushmarinov, Ivan S., Bruneau, Christian, Dixneuf, Pierre H., Osipov, Sergey N.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 27.09.2011
WILEY‐VCH Verlag
Subjects
pyridine derivatives
rearrangements
thiopyran derivatives
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Summary:Copper‐catalyzed tandem ylide formation—[2,3]‐sigmatropic rearrangement of CF3‐containing diazo compounds (II) with amines and sulfides containing two allyl and/or propargyl groups, e.g. (I), (V), (IX) or (XIII), affords the corresponding dienes, enynes or allenynes.
Bibliography:ark:/67375/WNG-6TW9ZL3G-3
istex:0D240D217B524DD2943DE8F9FD753D24177AD487
ArticleID:CHIN201139116
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201139116