ChemInform Abstract: SmI2-Mediated Radical Cyclizations Directed by a C-Si Bond

The silicon substituent, connected to carbon, plays a crucial role as controlling element to achieve the diastereoselective cyclization with formation of 2 or 3 stereocenters.

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Bibliographic Details
Published inChemInform Vol. 42; no. 12; p. no
Main Authors Harb, Hassan Y., Collins, Karl D., Altur, Jose V. Garcia, Bowker, Sue, Campbell, Leonie, Procter, David J.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 22.03.2011
WILEY‐VCH Verlag
Subjects
cyclobutane derivatives
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
furan derivatives
radical reactions
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Summary:The silicon substituent, connected to carbon, plays a crucial role as controlling element to achieve the diastereoselective cyclization with formation of 2 or 3 stereocenters.
Bibliography:ArticleID:CHIN201112093
istex:7B126FA7BC0EDCC3B28A750C430E169F4CA1F319
ark:/67375/WNG-5N6FSGKN-6
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201112093