Di­aqua­bis­(ethyl­enedi­amine)copper(II) bis­[tris­(ethyl­enedi­amine)­nickel(II)] tris­(naphthalene-2,6-di­sulfonate) tetrahydrate

The title mixed‐metal compound, [Cu(C2H8N2)2(H2O)2][Ni(C2H8N2)3]2(C10H6O6S2)3·4H2O, was obtained during investigations of the porous frameworks constructed by amino‐coordinated metal complex cations and large organic anions. All three naphthalene‐2,6‐di­sulfonate anions and the [Cu(en)2(H2O)2]2+ cat...

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Published inActa crystallographica. Section C, Crystal structure communications Vol. 57; no. 10; pp. 1168 - 1170
Main Authors Cai, Jiwen, Feng, Xiao-Long, Hu, Xiao-Peng
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01.10.2001
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Summary:The title mixed‐metal compound, [Cu(C2H8N2)2(H2O)2][Ni(C2H8N2)3]2(C10H6O6S2)3·4H2O, was obtained during investigations of the porous frameworks constructed by amino‐coordinated metal complex cations and large organic anions. All three naphthalene‐2,6‐di­sulfonate anions and the [Cu(en)2(H2O)2]2+ cation are located on crystallographic inversion centers and assemble into an extended two‐dimensional network through intermolecular hydrogen bonds, creating cavities in which the [Ni(en)3]2+ cations and water mol­ecules are included.
Bibliography:istex:105237B60ED6AE2462A44CC40A21142CC630C98E
ark:/67375/WNG-Z4XVZJ71-9
ArticleID:AYCFR1340
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270101013324