Correlating light and thermal stability of silver carboxylate complexes by infrared and 13C NMR spectroscopy

Bond nature of carboxylic groups can play an important role in Ag(I)-carboxylate compounds because light and thermal stability are important requirements for future applications such as antibacterial additives. A linear correlation between bond character and light stability of silver carboxylate com...

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Bibliographic Details
Published inJournal of coordination chemistry Vol. 69; no. 23; pp. 3472 - 3479
Main Authors Azócar, Manuel I., Aldabaldetrecu, Maialen, levin, Pedro, Tamayo, Laura, Guerrero, Juan, Páez, Maritza A.
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 01.12.2016
Taylor & Francis Ltd
Subjects
Fourier transform infrared spectroscopy (FTIR)
Fourier transforms
irradiation effects
NMR
Nuclear magnetic resonance
nuclear magnetic resonance (NMR)
Thermogravimetric analysis
thermogravimetric analysis (TGA)
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Summary:Bond nature of carboxylic groups can play an important role in Ag(I)-carboxylate compounds because light and thermal stability are important requirements for future applications such as antibacterial additives. A linear correlation between bond character and light stability of silver carboxylate complexes has been predicted by a direct relationship of infrared and 13 C NMR spectroscopic data. This correlation is in agreement with the thermogravimetric analysis and provides a new approach to explore the interaction and the physical properties of metal-carboxylate bonds.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958972.2016.1234610