Selective Formation of Imines by Aerobic Photocatalytic Oxidation of Amines on TiO2

An oxygenation pathway: The title transformation involves a two‐step process: a selective oxygenation step to generate aldehyde intermediates and a subsequent condensation step to afford the imine products (see scheme).

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 50; no. 17; pp. 3934 - 3937
Main Authors Lang, Xianjun, Ji, Hongwei, Chen, Chuncheng, Ma, Wanhong, Zhao, Jincai
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 18.04.2011
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Amines
Amines - chemistry
Catalysis
Chemistry
Chemistry, Multidisciplinary
imines
Imines - chemistry
Molecular Structure
Oxidants, Photochemical - chemistry
Oxidation-Reduction
photocatalysis
Photooxidation
Physical Sciences
Science & Technology
selective oxidation
Titanium - chemistry
Titanium dioxide
selective oxidation
ONE-POT
imines
CYCLOHEXANE
MONOAMINE-OXIDASE CATALYSIS
SUPPORTED GOLD
HETEROGENEOUS PHOTOCATALYSIS
BENZYLIC AMINES
ALCOHOLS
NANOPARTICLES
DEHYDROGENATION
titanium dioxide
photocatalysis
PHOTOOXIDATION
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Summary:An oxygenation pathway: The title transformation involves a two‐step process: a selective oxygenation step to generate aldehyde intermediates and a subsequent condensation step to afford the imine products (see scheme).
Bibliography:973 project - No. 2010CB933503; No. 2007CB613306
CAS
ArticleID:ANIE201007056
ark:/67375/WNG-SJBBH4KZ-2
NSFC - No. 20920102034; No. 21077110; No. 20877076
Financial support from the 973 project (nos. 2010CB933503 and 2007CB613306), the NSFC (nos. 20920102034, 21077110, and 20877076,) and the CAS are gratefully acknowledged.
istex:3055974796BDB44E4BDE0A9040A59289678A2AFA
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201007056