Synthesis and Characterization of Nanocrystalline SrTiO3

• Published in: Journal of the American Ceramic Society Vol. 89; no. 9; pp. 2804 - 2811
• Main Authors: Balaya, Palani, Ahrens, Martin, Kienle, Lorentz, Maier, Joachim, Rahmati, Behnaz, Lee, Sung Bo, Sigle, Wilfried, Pashkin, Alexej, Kuntscher, Christine, Dressel, Martin
• Format: Journal Article
• Language: English
• Published: Malden, USA Blackwell Publishing Inc 01.09.2006; Blackwell
• Subjects: Applied sciences; Building materials. Ceramics. Glasses; Ceramic industries; Chemical industry and chemicals; Cross-disciplinary physics: materials science; rheology; Electrotechnical and electronic ceramics; Exact sciences and technology; Materials science; Nanopowders; Nanoscale materials and structures: fabrication and characterization; Physics; Technical ceramics; Scanning electron microscopy; Electrical properties; Experimental study; X ray diffraction; Ultrafine powder; Precursor; Oxide ceramics; Characterization; Hot pressing; Dilatometry; Transmission electron microscopy; Sintering; Strontium titanates; Manufacturing; Chemical synthesis; Nanocrystal; Electroceramics
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/j.1551-2916.2006.01133.x

The synthesis and densification of fairly dense nanocrystalline SrTiO3 and its characterization are described in this paper in detail. Significant grain growth was avoided by the application of a two‐stage sintering process using hot pressing. High‐resolution transmission electron microscopy and electron energy loss spectroscopy characterizations indicate pure material with no detectable chemical inhomogeneities. The electrical measurements indicate the disappearance of bulk contribution to the electrical conduction due to the overlap of depleted space charge layers if the grain size is below 100 nm. Owing to the overlap, the capacitance appears as bulk‐like rather than due to space charge polarization. Non‐contact sub‐millimeter optical spectroscopy measurements reveal strong suppression of the dielectric constant values at low temperature.