Hierarchical β-Mo2C Nanotubes Organized by Ultrathin Nanosheets as a Highly Efficient Electrocatalyst for Hydrogen Production
Production of hydrogen by electrochemical water splitting has been hindered by the high cost of precious metal catalysts, such as Pt, for the hydrogen evolution reaction (HER). In this work, novel hierarchical β‐Mo2C nanotubes constructed from porous nanosheets have been fabricated and investigated...
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| Published in | Angewandte Chemie International Edition Vol. 54; no. 51; pp. 15395 - 15399 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
14.12.2015
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| Edition | International ed. in English |
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| Abstract | Production of hydrogen by electrochemical water splitting has been hindered by the high cost of precious metal catalysts, such as Pt, for the hydrogen evolution reaction (HER). In this work, novel hierarchical β‐Mo2C nanotubes constructed from porous nanosheets have been fabricated and investigated as a high‐performance and low‐cost electrocatalyst for HER. An unusual template‐engaged strategy has been utilized to controllably synthesize Mo‐polydopamine nanotubes, which are further converted into hierarchical β‐Mo2C nanotubes by direct carburization at high temperature. Benefitting from several structural advantages including ultrafine primary nanocrystallites, large exposed surface, fast charge transfer, and unique tubular structure, the as‐prepared hierarchical β‐Mo2C nanotubes exhibit excellent electrocatalytic performance for HER with small overpotential in both acidic and basic conditions, as well as remarkable stability.
From the same sheet: Hierarchical β‐Mo2C nanotubes constructed of ultrathin nanosheets are designed and synthesized. Benefitting from ultra‐small primary nanocrystallites, a large exposed surface, fast charge transfer, and unique tubular structure, the as‐prepared hierarchical β‐Mo2C nanotubes exhibit excellent electrocatalytic performance for the hydrogen evolution reaction. |
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| AbstractList | Production of hydrogen by electrochemical water splitting has been hindered by the high cost of precious metal catalysts, such as Pt, for the hydrogen evolution reaction (HER). In this work, novel hierarchical β‐Mo2C nanotubes constructed from porous nanosheets have been fabricated and investigated as a high‐performance and low‐cost electrocatalyst for HER. An unusual template‐engaged strategy has been utilized to controllably synthesize Mo‐polydopamine nanotubes, which are further converted into hierarchical β‐Mo2C nanotubes by direct carburization at high temperature. Benefitting from several structural advantages including ultrafine primary nanocrystallites, large exposed surface, fast charge transfer, and unique tubular structure, the as‐prepared hierarchical β‐Mo2C nanotubes exhibit excellent electrocatalytic performance for HER with small overpotential in both acidic and basic conditions, as well as remarkable stability.
From the same sheet: Hierarchical β‐Mo2C nanotubes constructed of ultrathin nanosheets are designed and synthesized. Benefitting from ultra‐small primary nanocrystallites, a large exposed surface, fast charge transfer, and unique tubular structure, the as‐prepared hierarchical β‐Mo2C nanotubes exhibit excellent electrocatalytic performance for the hydrogen evolution reaction. Production of hydrogen by electrochemical water splitting has been hindered by the high cost of precious metal catalysts, such as Pt, for the hydrogen evolution reaction (HER). In this work, novel hierarchical β‐Mo2C nanotubes constructed from porous nanosheets have been fabricated and investigated as a high‐performance and low‐cost electrocatalyst for HER. An unusual template‐engaged strategy has been utilized to controllably synthesize Mo‐polydopamine nanotubes, which are further converted into hierarchical β‐Mo2C nanotubes by direct carburization at high temperature. Benefitting from several structural advantages including ultrafine primary nanocrystallites, large exposed surface, fast charge transfer, and unique tubular structure, the as‐prepared hierarchical β‐Mo2C nanotubes exhibit excellent electrocatalytic performance for HER with small overpotential in both acidic and basic conditions, as well as remarkable stability. |
| Author | Lou, Xiong Wen (David) Ma, Fei-Xiang Xu, Cheng-Yan Wu, Hao Bin Xia, Bao Yu |
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| Snippet | Production of hydrogen by electrochemical water splitting has been hindered by the high cost of precious metal catalysts, such as Pt, for the hydrogen... |
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| SubjectTerms | Carburization (corrosion) Carburizing Catalysts Charge transfer electrocatalysis Electrocatalysts Electrochemistry High temperature Hydrogen hydrogen evolution reaction Hydrogen evolution reactions Hydrogen production molybdenum carbide Nanosheets Nanotechnology Nanotubes Structural hierarchy Surface charge Ultrafines Water splitting |
| Title | Hierarchical β-Mo2C Nanotubes Organized by Ultrathin Nanosheets as a Highly Efficient Electrocatalyst for Hydrogen Production |
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