Ferrocenyl Ligands with Two Phosphanyl Substituents in the α,ε positions for the Transition Metal Catalyzed Asymmetric Hydrogenation of Functionalized Double Bonds

The choice of the substituents at the benzylic position of diphosphane 1 allows the selection of the absolute configuration of the product that is obtained from the transition metal catalyzed enantioselective hydrogenation of various β‐dicarbonyl compounds, α‐acetamidocinnamic acid derivatives, and...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 38; no. 21; pp. 3212 - 3215
Main Authors Ireland, Tania, Grossheimann, Gabriele, Wieser-Jeunesse, Catherine, Knochel, Paul
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 02.11.1999
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Asymmetric catalysis
Asymmetry
Chemistry
Chemistry, Multidisciplinary
Derivatives
Dimethyl
Homogeneous catalysis
Hydrogenation
Hydrogenations
Ligands
Metallocenes
Phosphanes
Physical Sciences
Science & Technology
Transition metals
FERROCENYLDIPHOSPHINE
RHODIUM
homogeneous catalysis
ENANTIOSELECTIVE HYDROGENATION
asymmetric catalysis
phosphanes
hydrogenations
DERIVATIVES
DYNAMIC KINETIC RESOLUTION
metallocenes
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Summary:The choice of the substituents at the benzylic position of diphosphane 1 allows the selection of the absolute configuration of the product that is obtained from the transition metal catalyzed enantioselective hydrogenation of various β‐dicarbonyl compounds, α‐acetamidocinnamic acid derivatives, and dimethyl itaconate (see scheme).
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ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19991102)38:21<3212::AID-ANIE3212>3.0.CO;2-9